Oxatriphyrin(4.1.1)

M. Pawlicki, A Kędzia also observed formation of [18]triphyrin(4.1.1) derived from the specific reactivity of a furan entrapped in a macrocycle. Oxidative transformation of the final molecule gives two rigid lactams presenting structural factors of optically active compounds.

Further reading

Pawlicki, M.; Kędzia, A.; Szterenberg, L.; Latos-Grażyński, L. Expanded Triphyrin via a Carbacorrole Architecture. Eur. J. Org. Chem. 2013, 2770.