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Zespół chemii porfiryn i metaloporfiryn

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B. Szyszko obtained meso-anthriporphyrin, that is a carbaporphyrinoid with an anthracene ring embedded in the tripyrrolic framework.

Its coordination properties showed specific metal(II)–η2-CC interaction followed by unexpected C-C cleavage.

Photophysical properies of the thia derivative in conformational dependency was also a subject of investigations.

Further reading

Szyszko, B.; Latos-Grażyński, L.; Szterenberg, L. Toward Aceneporphyrinoids: Synthesis and Transformations of Palladium(II) meso-Anthriporphyrin. Chem. Commun. 201248, 5004

Sung, Y. M.; Szyszko, B.; Myśliborski, R.; Stępień, M.; Oh, J.; Son, M.; Latos-Grażyński, L.; Kim, D. The effect of π-conjugation in the macrocyclic ring on the photophysical properties of a series of thiaaceneporphyrinoids. Chem. Commun. 201450, 8367