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Zespół chemii porfiryn i metaloporfiryn

You are here: Molecules > Metalloceneporphyrins > Ruthenoceneporphyrin

Ruthenoceneporphyrin

The next step undertaken by I. Simkowa (Grocka) in merging of metalocene and porphyrinoid moieties was synthesis of ruthenoceneporphyrinoids.

The hingelike flexibility of ruthenocene plays the critical role as a determinant of aromaticity as exemplified by its aromatic synperiplanar and antiaromatic anticlinal(eclipsed) conformers of ruthenocenoporphyrinoids.

Further reading

Grocka, I.; Latos-Grażyński, L.; Stępień, M. Ruthenocenoporphyrinoids: Conformation Determines Macrocyclic π Conjugation Transmitted Across a d-Electron Metallocene. Angew. Chem. Int. Ed. 201352, 1078.