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Zespół chemii porfiryn i metaloporfiryn

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The incorporation of a phenanthrene moiety into a porphyrin framework achieved by B. Szyszko results in the formation of a hybrid macrocycle-phenanthriporphyrin-merging the structural features of polycyclic aromatic hydrocarbons and porphyrins. An antiaromatic aceneporphyrinoid, adopting the trianionic {CCNN} core, is suitable for the incorporation of a phosphorus(V) center to form a hypervalent organophosphorus(V) derivative.

Further reading

Szyszko, B.; Białońska, A.; Szterenberg, L.; Latos-Grażyński, L. Phenanthriporphyrin: Antiaromatic Aceneporphyrinoid as Surrounding for Hypervalent Organophosphorus(V). Angew. Chem. Int. Ed. 201554, 4932.