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Zespół chemii porfiryn i metaloporfiryn

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Subpyriporphyrin

Subpyriporphyrin was obtained by R. Myśliborski in an attempt to synthesize a pyridine containing expanded porphyrin.

Subpyriporphyrin is a novel type of contracted porphyrin - a homologue of [14]triphyrin(1.1.1) with a pyridine moiety embedded in the macrocyclic framework. X-ray crystal structure analysis showed that macrocycle is slightly ruffled.

Further reading

Myśliborski, R.; Latos-Grażyński, L.; Szterenberg, L.; Lis, T. Subpyriporphyrin - A [14]Triphyrin(1.1.1) Homologue with an Embedded Pyridine Moiety Angew. Chem. Int. Ed. 2006, 45, 3670.

(See the complete publication list of our group.)